Controlling self-assembled perovskite-spinel nanostructures.

نویسندگان

  • Haimei Zheng
  • Qian Zhan
  • Florin Zavaliche
  • Matt Sherburne
  • Florian Straub
  • Maria P Cruz
  • Long-Qing Chen
  • Uli Dahmen
  • R Ramesh
چکیده

We report a discovery that self-assembled perovskite-spinel nanostructures can be controlled simply by selecting single-crystal substrates with different orientations. In a model BiFeO(3)-CoFe(2)O(4) system, a (001) substrate results in rectangular-shaped CoFe(2)O(4) nanopillars in a BiFeO(3) matrix; in contrast, a (111) substrate leads to triangular-shaped BiFeO(3) nanopillars in a CoFe(2)O(4) matrix, irrespective of the volume fraction of the two phases. This dramatic reversal is attributed to the surface energy anisotropy as an intrinsic property of a crystal.

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عنوان ژورنال:
  • Nano letters

دوره 6 7  شماره 

صفحات  -

تاریخ انتشار 2006